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40g of sample use to be the absolute maximum for feeding into a 80ml grinding bowl. After 5 minutes of grinding, sample is sticking strongly to bowl and grinding balls.
This uses to happen after the majority of particles reached a fineness of < 20-30µm. Interacting forces between fine ground particles will become bigger as their own g-force. Therefore, particles will stick to each other and just become compressed by the used grinding balls. These clusters of particles also contain bigger particles which will not be ground any further too.
A longer dry grinding time is not recommended.
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